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Benzaldehyde
Synonyms:Almond artificial essential oil;almondartificialessentialoil;Artifical essential oil of almond;Artificial Almond Oil;Artificial bitter almond oil;artificialalmondoil;Benzaldehyde FFC;benzaldehydeffc
CAS:100-52-7
MF:C7H6OMW:106.12
EINECS:202-860-4Product Categories:Pharmaceutical Intermediates;BenzaldehydeMol File:100-52-7.mol
mp -26 °
Cbp 179 °C
density 1.05 vapor density 3.7 (vs air)
vapor pressure 4 mm Hg ( 45 °C)
FEMA 2127
vapor pressure 4 mm Hg ( 45 °C)
FEMA 2127
refractive index n20/D 1.545(lit.)
Fp 145 °F
Water Solubility <0.01 g/100 mL at 19.5 ºC
Fp 145 °F
Water Solubility <0.01 g/100 mL at 19.5 ºC
FreezingPoint -56℃Sensitive: Air Sensitive
Merck 14,1058
BRN 471223
Stability:Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, reducing agents, steam. Air, light and moisture-sensitive.
CAS DataBase Reference100-52-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzaldehyde(100-52-7)
EPA Substance Registry SystemBenzaldehyde(100-52-7)
Chemical Properties:Colorless to light yellow liquid
General Description:A clear colorless to yellow liquid with a bitter almond odor. Flash point near 145°F. More denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. The primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways. Used in flavoring and perfume making.
Air & Water Reactions:Oxidizes in air to form benzoic acid, which is moderately toxic by ingestion. Insoluble in water
Reactivity Profile:A nontoxic, combustible liquid, reacts with oxidizing reagents. Benzaldehyde must be blanketed with an inert gas at all times since Benzaldehyde is oxidized readily by air to benzoic acid [Kirk-Othmer, 3rd ed., Vol. 3, 1978, p. 736]. In contact with strong acids or bases Benzaldehyde will undergo an exothermic condensation reaction [Sax, 9th ed., 1996, p. 327]. A violent reaction was observed on contact with peroxyacids (peroxyformic acid) [DiAns, J. et al., Ber., 1915, 48, p. 1136]. An explosion occurred when pyrrolidine, Benzaldehyde, and propionic acid were heated to form porphyrins.
Health Hazard:Inhalation of concentrated vapor may irritate eyes, nose and throat. Liquid is irritating to the eyes. Prolonged contact with the skin may cause irritation.
Fire Hazard:HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
